{"created":"2025-02-13T05:05:45.964964+00:00","id":2000307,"links":{},"metadata":{"_buckets":{"deposit":"8e07e557-1a45-4304-b75d-82d5630bc669"},"_deposit":{"created_by":41,"id":"2000307","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2000307"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02000307","sets":["1730444918938"]},"author_link":[],"control_number":"2000307","item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Wigner-Witmer相関則の導出","subitem_title_language":"ja"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"山崎, 勝義","creatorNameLang":"ja"},{"creatorName":"Yamasaki, Katsuyoshi","creatorNameLang":"en"}],"familyNames":[{"familyName":"山崎","familyNameLang":"ja"},{"familyName":"Yamasaki","familyNameLang":"en"}],"givenNames":[{"givenName":"勝義","givenNameLang":"ja"},{"givenName":"Katsuyoshi","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2025 by Author","subitem_rights_language":"en"}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"Wigner-Witmer相関則","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"Building-up principle","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"構成原理","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"Term","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"等核2原子分子","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"分子を構成している各原子のterm(項) から,分子がとりうる電子状態のtermを決定するための原理である構成原理(building-up principle)は,G. Herzbergが著した,分子分光学のバイブルとも呼べる\"Molecular Spectra and Molecular Structure\"と題する3冊のテキスト(I～III)のうちの2冊(第I巻と第III巻)に詳しく説明されている。異核の2原子からなる2原子分子のterm決定に戸惑う部分はないが,等核2原子からできる2原子分子のterm決定においては\"超\"難解な点が存在する。たとえば,同種原子の同電子状態(^3S+^3S) からなる2原子分子のtermが,^1Σ^+_g,^3Σ^+_u,^5Σ^+_gになることが第I巻,p. 321のTable 28に記されているが,なぜ,スピン多重度ごとに反転対称性(g, u対称)が異なるのかわからないという疑問が発生する。Herzbergのテキストには,理由が「Wigner-Witmer相関則によって」と書かれているのみで,論理的な根拠や解説は述べられていない。本書は,分子分光学や量子化学の分野において基本的な重要事項の1つであるにもかかわらず,原理や導出に関する解説がほとんど行われることなく,最終結果だけが引用(利用)されてきたWigner-Witmer相関則を正確に理解するために書かれた monographである。","subitem_description_language":"ja","subitem_description_type":"Abstract"},{"subitem_description":"第7版第1刷","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"漁火書店","subitem_publisher_language":"ja"}]},"item_1617186660861":{"attribute_name":"Date","attribute_value_mlt":[{"subitem_date_issued_datetime":"2025-04-27","subitem_date_issued_type":"Created"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"book","resourceuri":"http://purl.org/coar/resource_type/c_2f33"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"第4版第8刷(2008)"}]},{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"第4版第12刷(2008)"}]},{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"第4版第16刷(2013)"}]},{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"第4版第17刷(2018)"}]},{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"第4版第18刷(2025)"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://home.hiroshima-u.ac.jp/kyam/pages/results/monograph/","subitem_relation_type_select":"URI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2025-05-09"}],"filename":"RefWig_Wit_7(1).pdf","filesize":[{"value":"743 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2000307/files/RefWig_Wit_7(1).pdf"},"version_id":"ebe7a530-480a-49f8-876b-d51e18ca6646"}]},"item_title":"Wigner-Witmer相関則の導出","item_type_id":"40003","owner":"41","path":["1730444918938"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2025-05-09"},"publish_date":"2025-05-09","publish_status":"0","recid":"2000307","relation_version_is_last":true,"title":["Wigner-Witmer相関則の導出"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-05-09T06:04:07.321291+00:00"}