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Pump-probe photodepletion spectroscopy of (C6H6)2+. Identification of spectrum in the charge resonance band region Ohashi, Kazuhiko Ohashi Kazuhiko Inokuchi, Yoshiya Inokuchi Yoshiya Nishi, Nobuyuki Nishi Nobuyuki open access Copyright (c) 1996 Elsevier Science B.V. All rights reserved 430 Pump-probe photodepletion (hole-burning) experiments are performed on mass-selected　cluster ions in the gas phase. An electronic spectrum of (C6H6)2+ in near-infrared region　comprises two charge resonance bands at 920 and 1160 nm. Intensities of these two bands　monitored by the probe laser are shown to be reduced by the same amount with the introduction of the pump laser. The behavior proves that the CR bands are due to two distinct transitions of a single isomer. No evidence is found for the existence of other isomers of (C6H6)2+. This work was supported in part by Grant-in-Aid for research programs (07740465 and 07454190) from the Ministry of Education, Science, Sports and Culture of Japan. K. O. received financial support from the Morino Science Foundation. This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 1996, available online: http://doi.org/10.1016/S0009-2614(96)01209-2 Elsevier B.V. 1996-12-06 eng journal article AO https://hiroshima.repo.nii.ac.jp/records/2006609 10.1016/S0009-2614(96)01209-2 http://doi.org/10.1016/S0009-2614(96)01209-2 0009-2614 Chemical Physics Letters Chemical Physics Letters 263 1–2 167 167 172 https://hiroshima.repo.nii.ac.jp/record/2006609/files/ChemPhysLett_1996_263_167.pdf 194.6 KB